The GWP has been defined as the ratio of the time-integrated
radiative forcing from the instantaneous release of 1 kg of a trace
substance relative to that of 1 kg of a reference gas (IPCC, l990):
---formula---
where TH is the time horizon over which the calculation is
considered, ax is the radiative efficiency due to a unit increase
in atmospheric abundance of the substance in question (i.e.,
Wm−2 kg−1), [x(t)] is the time-dependent decay in abundance of
the instantaneous release of the substance, and the corresponding
quantities for the reference gas are in the denominator. The GWP
of any substance therefore expresses the integrated forcing of a
pulse (of given small mass) of that substance relative to the
integrated forcing of a pulse (of the same mass) of the reference
gas over some time horizon. The numerator of Equation 6.2 is the
absolute (rather than relative) GWP of a given substance, referred
to as the AGWP. The GWPs of various greenhouse gases can then
be easily compared to determine which will cause the greatest
integrated radiative forcing over the time horizon of interest. The
direct relative radiative forcings per ppbv are derived from
infrared radiative transfer models based on laboratory measurements
of the molecular properties of each substance and considering
the molecular weights.