Results 1 to 2 of 2

Thread: Non-Polar Solvents and Solutes

  1. #1 Non-Polar Solvents and Solutes 
    New Member
    Join Date
    Mar 2010
    I'm having a difficult time really understanding how a non-polar solute dissolves in a non-polar solvent.

    My understanding of dissolution stems from how NaCl dissolves in water. The water molecules cause the Na+ ion and the Cl- ion to disassociate from one another because of the polar nature of water. Thus water dissolves NaCl.

    When I try to apply this concept to a non-polar solvent and solute however, it doesn't work. If the solute and solvent are both non-polar, they really do not interact with each other at all except for intermolecular interactions. Where exactly is the dissolution?

    Is my understanding of dissolution incorrect or incomplete, or is there something else I'm missing that is making it hard for me to understand the concept?

    Reply With Quote  


  3. #2  
    Forum Professor
    Join Date
    May 2005
    Dissolving a non-polar solute in a non-polar solvent is usually driven by entropy. The entropy of the system goes up if the solid dissolves into the liquid, so it does. Remember that dG=dH-TdS. With a salt dissolving in water, there's a major dH (enthalpy) component driving the process. With non-polar things, there's still the dS (entropy) component.

    Reply With Quote  

Posting Permissions
  • You may not post new threads
  • You may not post replies
  • You may not post attachments
  • You may not edit your posts